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CAS

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BENZYL 3-BROMOPROPYL ETHER is an organic compound that belongs to the class of ethers. It is characterized by its clear colorless to yellow liquid appearance and is utilized in various chemical synthesis processes due to its unique chemical properties.

54314-84-0

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54314-84-0 Usage

Uses

Used in Pharmaceutical and Chemical Research:
BENZYL 3-BROMOPROPYL ETHER is used as a synthetic intermediate for the preparation of various complex organic molecules. Its application is crucial in the development of new pharmaceutical compounds and the advancement of chemical research.
Used in the Synthesis of (2S,3S)-1-[(triisopropylsilyl)oxy]-7-(benzyloxy)-2,3-(isopropylidenedioxy)-4(Z)-heptene:
BENZYL 3-BROMOPROPYL ETHER serves as a key component in the synthesis process of this specific organic compound, which may have potential applications in the pharmaceutical industry.
Used in the Preparation of 5-(3-Benzyloxypropoxy)psoralen (PAP-7):
This ether is used as a reactant in the preparation of PAP-7, a compound that may have significance in the field of photochemistry and pharmaceuticals.
Used in the Total Synthesis of Zincophorin:
BENZYL 3-BROMOPROPYL ETHER is employed as an essential building block in the total synthesis of zincophorin, a complex organic molecule with potential applications in various fields.
Used in the Total Synthesis of (+)-Anatoxin-a:
This ether is also utilized in the total synthesis of (+)-anatoxin-a, a naturally occurring organic compound with potential applications in the study of biological systems and the development of new pharmaceuticals.

Check Digit Verification of cas no

The CAS Registry Mumber 54314-84-0 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 5,4,3,1 and 4 respectively; the second part has 2 digits, 8 and 4 respectively.
Calculate Digit Verification of CAS Registry Number 54314-84:
(7*5)+(6*4)+(5*3)+(4*1)+(3*4)+(2*8)+(1*4)=110
110 % 10 = 0
So 54314-84-0 is a valid CAS Registry Number.
InChI:InChI=1/C10H13BrO/c11-7-4-8-12-9-10-5-2-1-3-6-10/h1-3,5-6H,4,7-9H2

54314-84-0 Well-known Company Product Price

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  • Alfa Aesar

  • (H66278)  Benzyl 3-bromopropyl ether, 95%   

  • 54314-84-0

  • 1g

  • 242.0CNY

  • Detail
  • Alfa Aesar

  • (H66278)  Benzyl 3-bromopropyl ether, 95%   

  • 54314-84-0

  • 5g

  • 970.0CNY

  • Detail

54314-84-0SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 12, 2017

Revision Date: Aug 12, 2017

1.Identification

1.1 GHS Product identifier

Product name 3-(Benzyloxy)propyl Bromide

1.2 Other means of identification

Product number -
Other names 3-bromopropoxymethylbenzene

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:54314-84-0 SDS

54314-84-0Relevant articles and documents

Synthesis of the Core Structure of Palhinine A

Gaugele, Dominik,Maier, Martin E.

, p. 2549 - 2556 (2021/06/28)

We present a strategy to the core structure of the alkaloid palhinine A passing through a 2,5-difunctionalized cyclohexenone. This enone was prepared by a domino Michael/aldol condensation sequence. An allylation reaction on the cyclohexenone followed by

Selective alkyl ether cleavage by cationic bis(phosphine)iridium complexes

Jones, Caleb A. H.,Schley, Nathan D.

supporting information, p. 1744 - 1748 (2019/02/20)

Catalysts capable of heterolytic silane activation have been successfully applied to the conversion of alkyl ethers to silyl ethers via C-O bond cleavage. The previously-reported cationic pincer-supported iridium complex for this transformation suffers fr

Photocatalyic Appel reaction enabled by copper-based complexes in continuous flow

Minozzi, Clémentine,Grenier-Petel, Jean-Christophe,Parisien-Collette, Shawn,Collins, Shawn K.

supporting information, p. 2730 - 2736 (2018/11/21)

A copper-based photocatalyst, Cu(tmp)(BINAP)BF4, was found to be active in a photoredox Appel-type conversion of alcohols to bromides. The catalyst was identified from a screening of 50 complexes and promoted the transformation of primary and secondary alcohols to their corresponding bromides and carboxylic acids to their anhydrides. The protocol was also amendable and optimized under continuous flow conditions.

A concise stereoselective synthesis of (+)-1-deoxy-6-epi-castanospermine

Gajare, Vikas S.,Khobare, Sandip R.,Datrika, Rajender,Reddy, K. Srinivasa,Rajana, Nagaraju,Babu, B. Kishore,Rao, B. Venkateswara,Syam Kumar

supporting information, p. 1486 - 1488 (2016/03/12)

A concise stereoselective synthesis of (+)-1-deoxy-6-epi-castanospermine has been developed through stereoselective approach from the chiral precursor R-Glycidol. The key steps in the synthesis involve Grignard reaction through Weinreb amide, followed by Sharpless dihydroxylation and stereoselective reduction of imine assigned the required stereochemical feature of indolizidine azasugar (+)-1-deoxy-6-epi-castanospermine.

Light-mediated deoxygenation of alcohols with a dimeric gold catalyst

McCallum, Terry,Slavko, Ekaterina,Morin, Mathieu,Barriault, Louis

supporting information, p. 81 - 85 (2015/02/18)

A new protocol for the reductive deoxygenation of primary alcohols was explored. This photo-mediated method combines a novel approach to bromination of alcohols merged with the powerful reducing capability of [Au2(dppm)2]Cl2 [dppm = 1,1-bis(diphenylphosphino)methane] as a photoredox catalyst. The highly efficient methods discussed are marked by the use of UVA light-emitting diodes, which have significantly reduced reaction times and lowered setup cost.

Synthetic studies on lycopodine: Construction of hexahydrojulolidine core by intramolecular Mannich reaction

Sato, Takanao,Ueda, Hirofumi,Tokuyama, Hidetoshi

supporting information, p. 7177 - 7180 (2015/01/09)

The tricyclic core skeleton of lycopodine was constructed by the intramolecular Mannich reaction of a 12-membered cyclic amine. The concise assembly of the macrocyclic intermediate was executed by the sequential inter- and intramolecular N-alkylation of a

Syntheses of the Stemona alkaloids (±)-stenine, (±)- neostenine, and (±)-13-epineostenine using a stereodivergent Diels-Alder/azido-Schmidt reaction

Frankowski, Kevin J.,Golden, Jennifer E.,Zeng, Yibin,Lei, Yao,Aube, Jeffrey

, p. 6018 - 6024 (2008/09/20)

A tandem Diels-Alder/azido-Schmidt reaction sequence provides rapid access to the core skeleton shared by several Stemona alkaloids including stenine, neostenine, tuberostemonine, and neotuberostemonine. The discovery and evolution of inter- and intramole

BORON-CONTAINING SMALL MOLECULES

-

Page/Page column 220, (2009/01/23)

This invention provides, among other things, novel compounds useful for treating bacterial infections, pharmaceutical compositions containing such compounds, as well as combinations of these compounds with at least one additional therapeutically effective agent.

A combined intramolecular Diels-Alder/intramolecular Schmidt reaction: Formal synthesis of (±)-stenine

Golden, Jennifer E.,Aube, Jeffrey

, p. 4316 - 4318 (2007/10/03)

Four stereocenters and three rings are established in one step in a new formal synthesis of (±)-stenine (see scheme). This key reaction cascade consists of an intramolecular Diels-Alder reaction followed by an intramolecular Schmidt reaction. The resultin

Etherification of alkoxydialkylsilanes with carbonyl compounds

Jiang, Xinglong,Bajwa, Joginder S,Slade, Joel,Prasad, Kapa,Repi?, Oljan,Blacklock, Thomas J

, p. 9225 - 9227 (2007/10/03)

A novel method for preparing ethers from alkoxydialkylsilanes and carbonyl compounds through reductive etherification is described. The salient feature in this method is the utilization of internal hydrogen as the hydride source for reducing the oxonium intermediate generated by using the Cl(R)2SiBr[BiBr3/Cl(R)2SiH] catalytic system.

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